Sulfuric Acid

Sulfuric Acid: The King of Chemicals

Sulfuric acid (H₂SO₄) is often referred to as the “king of chemicals” due to its massive industrial importance and role in producing countless other chemicals. It is one of the strongest mineral acids, widely used in industries, laboratories, and manufacturing processes. Its versatility, reactivity, and dehydrating properties make it a cornerstone of modern chemistry.


What is Sulfuric Acid?

Sulfuric acid is a dense, oily, colorless to slightly yellow liquid, known for being highly corrosive and reactive. It is a strong diprotic acid, meaning it can donate two protons (H⁺) in aqueous solution, and it also acts as a powerful oxidizing and dehydrating agent.

Chemical Formula: H₂SO₄

Molecular Weight: 98.08 g/mol

CAS Number: 7664-93-9

Other Names: Oil of vitriol, battery acid (diluted)


Physical and Chemical Properties

Property Value
Appearance Clear to slightly yellow viscous liquid
Odor Odorless (but choking fumes when hot)
Density (98%) ~1.84 g/cm³
Boiling Point ~337 °C (decomposes before boiling)
Freezing Point ~10.3 °C
pKa1 / pKa2 ~ -3 / 1.99
Solubility Miscible with water (exothermic)

 

Caution: Always add acid to water, not the other way around, to prevent violent reactions and splashing.


Types and Concentrations

  1. Concentrated Sulfuric Acid (98%)

    • Used in industrial processes and laboratories

  2. Battery Acid (30–35%)

    • Found in lead-acid batteries

  3. Dilute Sulfuric Acid (≤10%)

    • Used in chemical education, cleaning agents, and neutralization


Major Applications of Sulfuric Acid

1. Fertilizer Industry

  • Used in the production of phosphoric acid, which is then used to make phosphate fertilizers like superphosphate and ammonium phosphate

2. Chemical Manufacturing

  • Key raw material in producing:

    • Hydrochloric acid

    • Nitric acid

    • Sulfonic acids

    • Synthetic detergents

3. Petroleum Refining

  • Used in alkylation processes and removing impurities from fuels

4. Batteries

5. Metallurgy

  • Employed in ore processingmetal pickling, and descaling iron and steel

6. Textile and Dyeing Industry

  • Used for pH adjustmentbleaching, and preparation of fibers

7. Cleaning and Descaling


Laboratory Uses

  • Dehydrating agent (removes water from compounds, even sugars)

  • Oxidizer (concentrated form can char organic materials)

  • Used in acid-base titrations and preparation of acid solutions


Safety and Handling

Sulfuric acid is highly corrosive and can cause severe chemical burns and thermal injury upon contact. Proper precautions are essential.

Health Hazards:

  • Skin/Eye Contact: Severe burns and permanent damage

  • Inhalation: Irritating to respiratory system; can cause pulmonary edema

  • Ingestion: Corrosive to mucous membranes and internal organs

Precautionary Measures:

  • Wear acid-resistant gloves, goggles, and lab coat

  • Always use in a well-ventilated area or fume hood

  • Store in non-metal, corrosion-resistant containers

  • Keep away from organic materials, bases, water, and oxidizers


Environmental Considerations

  • Releases sulfur oxides (SOx)contributing to acid rain

  • Spills can severely damage soil and aquatic life

  • Disposal must follow hazardous waste protocols


Conclusion

Sulfuric acid is one of the most important industrial chemicals, with applications that touch nearly every sector—from agriculture and automotive to textiles and electronics. While it is essential for economic development and modern living, sulfuric acid is also dangerously reactive and corrosive, requiring careful storage, handling, and disposal.

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